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改性鋼渣超細粉/石木塑復合材料的性能及補強-阻燃機理

The properties and reinforcement-flame retardant mechanism of modified steel slag ultrafine powder/stone-wood plastic composite materials

  • 摘要: 為實現冶金固廢鋼渣的高值化利用并提升石木塑復合材料的綜合性能。利用自制助磨劑與鋼渣復合進行超細立磨,并采用硅烷偶聯劑對其進行改性,制得改性鋼渣超細粉(MSSP),部分替代滑石粉用于制備石木塑復合材料。研究MSSP對石木塑復合材料力學、阻燃性能的影響及其機理。研究結果表明:當MSSP替代50 %的滑石粉時,石木塑復合材料獲得了最佳的力學性能和阻燃效果,與純滑石粉/石木塑復合材料相比,其拉伸強度、彎曲強度、沖擊強度分別提高55.5 %、36.3 %、76.7 %;水平燃燒速度和垂直燃燒的余焰時間及余灼時間顯著下降,氧指數提高22.8 %。通過硅烷偶聯劑改性,有效改善了MSSP與石木塑有機界面的相容性。MSSP均勻分布并接枝到聚乙烯和木粉分子鏈上,增強與基體相互作用,MSSP含有的高硬度、高熔點物質促進了石木塑體系內部的應力傳遞,增強了石木塑復合材料的力學性能;燃燒過程中與聚乙烯、木粉等的殘留物迅速凝聚形成致密穩定的保護炭層,進一步增強了材料的阻燃性能,實現了補強-阻燃的雙重效果。本研究為鋼渣高值化利用開辟了新途徑,為推動資源循環利用和可持續發展作貢獻。

     

    Abstract: In order to realize the high-value utilization of metallurgical solid waste steel slag and enhance the comprehensive performance of stone-wood plastic composites. Using homemade grinding aids and steel slag composite for ultrafine vertical milling, and silane coupling agent for its modification, produced modified steel slag superfine powder (MSSP), partially replacing talcum powder used in the preparation of stone-wood plastic composites. The effect of MSSP on the mechanical and flame retardant properties of stone-wood plastic composites and its mechanism were studied. The results showed that when MSSP replaced 50 % of talc, the stone-wood plastic composites obtained the best mechanical properties and flame retardant effect, and compared with pure talc/stone-wood plastic composites, its tensile strength, flexural strength and impact strength increased by 55.5 %, 36.3 % and 76.7 %, respectively; the horizontal combustion speed and vertical combustion after-flame time and after-scorching time were significantly reduced, and the oxygen index increased by 22.8%. Through the modification of silane coupling agent, the compatibility between MSSP and stone-wood plastic organic interface was effectively improved; MSSP was uniformly distributed and grafted to the molecular chain of polyethylene and wood powder to enhance the interaction with the matrix, and the high hardness and high melting point of MSSP promoted the stress transfer within the stone-wood plastic system, which strengthened the mechanical properties of the stone-wood plastic composite material; the residues with polyethylene and wood powder in the combustion process rapidly coalesced to form a dense and stable protection. During the combustion process and the residue of polyethylene, wood powder, etc., a dense and stable protective charcoal layer is formed quickly, which further enhances the flame retardant property of the material and realizes the dual effect of reinforcement - flame retardant. This study opens up a new way for the high-value utilization of steel slag and contributes to the promotion of resource recycling and sustainable development.

     

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