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電解水制氫技術:進展、挑戰與未來展望

Hydrogen production by water electrolysis: Advances, challenges and future prospects

  • 摘要: 實現全球碳中和是各國在2050年制定的重要目標之一,旨在減緩氣候變化的不良影響. 氫能作為一種極具潛力的清潔能源,憑借其高能量密度、零碳排放、可再生性強等特性,被視為實現能源轉型與應對氣候變化的重要載體. 為了實現這些目標,利用電解水制取氫氣已經成為解決全球碳中和問題的重要關鍵方案之一. 本文綜述了堿性電解水、質子交換膜電解水、陰離子交換膜電解水和固體氧化物電解水制氫技術的最新進展,并對這四種電解水技術的工作原理、結構特點以及優缺點進行了詳盡比較. 此外,總結了電解水制氫催化劑材料的研究進展,尤其是新型材料的開發與結構優化,旨在提升材料的催化活性與穩定性. 討論了海水電解制氫和耦合制氫等新興技術,強調通過電解質組成優化、高效雙功能催化劑開發及利用小分子氧化反應熱力學優勢,可有效提升電解水制氫效率和系統穩定性. 最后,提出了電解水制氫技術的發展趨勢與未來研究方向,包括提升催化劑性能、降低電解過程能耗、開發新型電解設備等,旨在促進電解水制氫技術的進步,助力全球碳中和目標的實現,并為未來的研究提供參考與指導.

     

    Abstract: Achieving global carbon neutrality is one of the key targets set by countries in 2050 to mitigate the adverse effects of climate change. As a clean energy with great potential, hydrogen energy is an important energy solution for this transition because of its high energy density, zero carbon emission, and strong renewability. Electrolytic water hydrogen production has emerged as a key solution for achieving global carbon neutrality goals. This paper investigates the progress and potential of various electrolysis methods, including alkaline water electrolysis, proton exchange membrane (PEM) electrolysis, anion exchange membrane (AEM) electrolysis, and solid oxide electrolyzer cell (SOEC) electrolysis, alongside emerging technologies such as seawater electrolysis and coupled hydrogen production. Alkaline electrolytic water hydrogen production technology occupies an important position in industrial applications owing to its high maturity, low cost and reliability, yet it faces challenges such as current density and gas cross-mixing. PEM technology, known for its high current density, gas purity, and compactness, is hindered by high costs and material corrosion. AEM technology offers cost benefits by avoiding precious metal catalysts and being compatible with low-concentration electrolytes; however, its development is still in the early stages. SOEC technology is promising for its high efficiency at high temperatures but is still in the experimental stage owing to issues such as catalyst deactivation and equipment lifespan. In addition, innovative methods such as seawater electrolysis and coupled hydrogen production offer a sustainable hydrogen production path, although seawater treatment poses technical challenges. Coupled hydrogen production, which links with other small molecule oxidation reactions, improves hydrogen production efficiency but requires further advancements in electrode material selection and reaction rate optimization. Moreover, research is focused on electrolyte additives, such as sulfates, carbonates, and other anionic inhibitors, to improve electrolysis efficiency and reduce corrosion. In catalyst development, new materials and structural improvements are under exploration for improving catalyst activity, stability, and cost-effectiveness. By optimizing system design and component synergy, electrolysis technology for hydrogen production is developing toward improved catalyst performance, reduced energy consumption, and efficient equipment. In particular, integrating electrolytic hydrogen production with renewable energy systems, such as solar and wind, offers an environment-friendly and economical hydrogen production model. In summary, this paper summarizes the current achievements and challenges in electrolysis technology for hydrogen production and provides a valuable reference for future research directions. As science and technology progress, electrolysis technology for hydrogen production will significantly contribute to global carbon neutrality. Governments should implement more supporting policies to promote the commercial application and market growth of this technology, ensuring that it can play a more important role in the future energy transition.

     

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