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低濃度稀土離子吸附材料研究進展

Research advances in low-concentration rare earth ion adsorption materials

  • 摘要: 近年來,隨著稀土產量與需求之間的供需矛盾日益加深,對稀土資源的高效綠色提取和分離提出了更高的要求. 特別是從稀土礦選礦廢水、精煉廢水、海水和溫泉等低濃度的稀土溶液中回收稀土資源已成為研究熱點. 相比于蒸發結晶、化學沉淀、溶劑萃取等傳統提取技術,吸附法因具有操作簡單、成本低廉、處理量大和適應性強等優勢,成為低濃度稀土深度回收的潛在方法之一. 本文匯總了近年來國內外有關于稀土離子吸附材料的研究進展,詳細介紹了礦物基、碳基、金屬?有機框架基和高分子基等吸附材料的設計與合成思路、微觀形貌、吸附行為、材料性能和潛在的應用潛力. 最后,對比指出了各種吸附材料的優勢和不足,提出開發面向應用的高效綠色靶向吸附材料是未來稀土吸附材料的主要發展趨勢,靶向吸附技術也將成為低濃度稀土溶液(廢水)資源化的主要方法,以期為稀土資源的高效利用提供參考.

     

    Abstract: Recently, with the persistently increasing demand and production of rare earth metals, the efficient and green recovery of rare earth resources has encouraged higher requirements. Particularly, the recovery of rare earth elements (REEs) from low-concentration rare earth solutions such as rare earth mineral processing wastewater, refining wastewater, seawater, and hot springs has become a research hotspot. Compared with conventional extraction methods, such as evaporative crystallization, chemical precipitation, and solvent extraction, adsorption holds promise for low-concentration rare earth recovery due to its advantages of simple operation, low cost, large treatment capacity, and strong adaptability. This paper meticulously outlines the recent research advancements on rare earth ion adsorption materials and introduces mineral-based, carbon-based, metal–organic framework (MOF)-based, and polymer-based adsorbents and their design ideas, microscopic morphologies (specific surface area, pore size, and particle geometric dimension), adsorption behaviors (adsorption kinetics and adsorption isotherm), material performances (maximum adsorption capacity, adsorption–desorption cycles, and stability), and potential applications (pH, dosage, coexisting competing ions, and actual REE wastewater treatment effect). Mineral-based adsorbent materials are characterized by clay minerals of layered silicate type; carbon-based adsorbent materials include biochar, graphene, and carbon nanotubes; MOF materials include the Zeolitic imidazolate framework (ZIF), University of Oslo (UIO), Materials of Institut Lavoisier (MIL), and Hong Kong University of Science and Technology (HKUST) series; polymer-based materials include natural and artificial polymers and hydrogels. Single-material adsorbents usually have low adsorption capacity, poor selectivity, and weak mechanical strength and are unstable under acidic conditions. To overcome these disadvantages, composite materials can be prepared, which capitalize on the benefits of their individual materials, e.g., use of polymer hydrogels loaded with fine-grained mineral materials to prevent agglomeration, in-situ MOF growth on the surface of graphene oxide to improve its stability in acidic conditions, use of polymers with specific functional groups that contain O, N, and P to alter porous materials to improve adsorption capacity, and magnetization modification of carbon-based materials and polymers to facilitate the subsequent recycling. Finally, the following future development trends of rare earth adsorbents are proposed: 1) development of green adsorbent materials, including green raw materials and no new pollution in the process, 2) development of highly selective adsorbent materials that can extract REEs from competing impurity ions and achieve the separation of a single rare earth among the REEs, and 3) development of high-efficiency adsorbent materials including REE extraction from low-concentration rare earth solutions and fast adsorption kinetics and their applications in the field of REE wastewater treatment.

     

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