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Y2O3彌散強化高速鋼的激光選區熔化制備及性能

Research of selective laser melting process and properties of Y2O3 dispersion strengthened high speed steel

  • 摘要: 為提高高速鋼的綜合性能,利用行星式球磨機將M2高速鋼(W6Mo5Cr4V2)粉體與納米尺寸的Y2O3顆粒進行低能球磨混合,并采用激光選區熔化制備Y2O3彌散強化M2高速鋼. 實驗結果表明,球磨后的M2高速鋼粉體基本呈球形,未發生嚴重變形,表面嵌布大量納米級Y2O3顆粒. 激光選區熔化成形的Y2O3彌散強化M2高速鋼試樣的致密度為98.3%,縱向微觀組織主要為等軸晶和柱狀枝晶,橫向微觀組織為等軸晶,平均晶粒尺寸為900 nm. X射線衍射結果顯示Y2O3顆粒的加入對M2高速鋼物相種類影響不大,仍由馬氏體相、殘余奧氏體相和碳化物組成. 其抗拉強度達到了943 MPa,與未添加Y2O3顆粒的高速鋼相比,強度提高了36%.

     

    Abstract: M2 high speed steel (W6Mo5Cr4V2) is an important engineering material, and with modern industry progressing, increased requirements are put forward for improved performance of high speed steel. To improve its comprehensive properties, M2 high speed steel powder is mixed with nano-sized Y2O3 particles through mechanical alloying. This mixture is then used to create Y2O3 dispersion strengthened M2 high speed steel by selective laser melting (SLM) electrometallurgy technology. The process parameters for SLM are as follows: laser power of 220 W, scanning speed of 800 mm·s?1, powder layer thickness of 0.03 mm, scanning spacing of 0.1 mm, and a substrate preheating temperature of 200 ℃. The effects of Y2O3 particles on the microstructure and mechanical properties of the prepared high speed steel were investigated using various techniques, including optical microscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, and mechanical property tests. Experimental results show that after low-energy ball milling, the M2 high speed steel powder remains mostly spherical with minimal deformation, preventing uneven spreading during the powder laying process. The surface of M2 high speed steel powder is coated with a large number of nanometer-sized Y2O3 particles. The relative density of Y2O3 dispersion strengthened samples formed by SLM is 98.3%. These samples exhibit a relatively smooth surface without obvious cracks, and the quality of the top surface quality is better than that of the side surfaces. The material’s basic structure and morphology are influenced by the molten pool and channel. Hexagonal honeycomb grains are evident in the molten channel, with fine grains distributed at the edges and slightly larger grains inside. The molten pool consists mainly of equiaxed crystals at the center and columnar dendrites at the boundaries, with grains growing epitaxially along the molten pool boundary. EDS (energy dispersive spectrometer) results show that elements Y and O are evenly distributed within the matrix, with no significant segregation. Subsequently, phase analysis reveals that adding Y2O3 particles has little effect on the phase composition of M2 high speed steel, which remains mainly martensite, residual austenite, and carbides. Owing to the small amount of Y2O3 added, no diffraction peaks of Y2O3 were found in the detection range. TEM results show that Y2O3 particles are larger at grain boundaries, reaching up to 90 nm, while smaller nanoparticles are diffusely distributed within the grains. Mechanical testing indicates that Y2O3 dispersion strengthened high speed steel samples fabricated by SLM exhibit good mechanical properties, with tensile strength reaching 943 MPa, a 36% increase compared to M2 high speed steel without Y2O3 particles. Its fracture surface is flat with a few cleavage steps and columnar crystals, indicating brittle fracture behavior. The addition of Y2O3 particles produces a larger number of nucleation sites, refines grain size, and hinders dislocation movement, preventing crack propagation along grain boundaries, thereby enhancing the mechanical properties of M2 high speed steel.

     

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