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第二相粒子與織構對高強Cu-Ni-Si系合金薄板各向異性的影響

Effects of precipitates and texture on the anisotropy of high-strength Cu-Ni-Si alloy sheets

  • 摘要: 利用利用X射線衍射、電子背散射衍射和透射電子顯微鏡等手段研究了Cu-Ni-Si系合金在不同固溶溫度下第二相與織構對其平面各向異性的影響.結果表明:隨固溶溫度的升高,合金強度和伸長率均出現先升高后降低的趨勢,且存在明顯的各向異性;800℃固溶時,Cu'和S'為主織構,部分形變晶粒誘發少量Brass、Goss和011〈511〉取向的形成,使得合金各向異性減弱;高溫固溶時(≥ 850℃),晶粒發生完全再結晶,Cu'和S'織構強度顯著增加,Brass等織構減弱甚至消失,各向異性增強;850℃固溶時效后形成δ-Ni2Si析出相,并與基體滿足001Cu//110δ,(010)Cu//(001)δ位向關系,溫度進一步增加,第二相析出體積分數降低,有利于改善材料的各向異性.

     

    Abstract: The effects of texture and precipitates on the plane anisotropy of Cu-Ni-Si alloy under different solid-solution temperature conditions were investigated by X-ray diffraction, electron backscattered diffraction, and transmission electron microscopy. The results show that strength and elongation first increase and then decrease with increasing solid-solution temperature, exhibiting apparently anisotropy. After 800℃ solid solution, the Cu' and S' are mainly texture and the alloy has weak anisotropic properties, which correlates with the coexistence of Brass, Goss, and 011〈511〉orientation owing to deformed grains. Complete recrystallization can be obtained at high temperature solution (≥ 850℃), the Cu' and S' texture intensity increases, whereas the Brass texture weakens and disappears and the anisotropy increases. δ-Ni2Si precipitation is observed after 850℃ solution and subsequent aging, and the crystal orientation between the matrix and precipitates is 001Cu//110δ and (010)Cu//(001)δ. The fraction of nanosize precipitates decreases significantly with increasing temperature and this improves the anisotropy.

     

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