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添加Al2O3-ZrO2復合粉改性氧化鋯質定徑水口及其損毀機理

Damage mechanism of zirconia metering nozzles modified by Al2O3-ZrO2 composite powder

  • 摘要: 通過添加溶膠-凝膠法制備的Al2O3-ZrO2復合粉,對陶瓷型和顆粒型氧化鋯質定徑水口進行改性.對比研究了陶瓷型和顆粒型定徑水口改性前后物理性能,礦物相組成和顯微結構的變化,并通過現場連鑄實驗對四種定徑水口損毀機理進行了探討.結果表明:相較于顆粒型定徑水口,陶瓷型定徑水口的顯氣孔率較低,體積密度和耐壓強度較高,熱震穩定性較差,抗侵蝕和沖刷性能較好.通過添加Al2O3-ZrO2復合粉改性后的定徑水口顯氣孔率降低,體積密度增加,耐壓強度提高,顆粒型定徑水口的熱震穩定性有了較大的提升,熱震次數約為改性前的1.5倍以上.通過對連鑄現場實際使用35 h后的殘樣分析發現,陶瓷型水口損毀主要是由于熱震穩定性差導致使用時發生炸裂,炸裂產生的裂紋引起一定程度的剝落和擴徑.未改性顆粒型定徑水口由于強度低和顯氣孔率高,剝落和擴徑更為嚴重,添加Al2O3-ZrO2復合粉改性后生成的鎂鋁尖晶石增強相大幅度提高了顆粒水口的熱震穩定性和抗沖刷侵蝕性能,連鑄現場使用后幾乎未擴徑.

     

    Abstract: The modified metering nozzles were fabricated by using sol-gel Al2O3-ZrO2 composite powder as additives in particle and ceramic type zirconia metering nozzles. The physical properties, mineral phase and microstructure of metering nozzles of particle and ceramic types before and after modification were studied and the damage mechanism of nozzles in continuous casting field test was analyzed. The results show that the ceramic type metering nozzle has lower apparent porosity, higher bulk density, higher compression strength and poorer thermal shock stability compared with the particle type metering nozzle. By adding Al2O3-ZrO2 composite powder, the apparent porosity of modified nozzles decreases, the bulk density and compression strength get higher, the thermal shock resistance of the particle type metering nozzle improves markedly, and the count of thermal shocks is about 1.5 times of that before modification. After the analysis of residual samples in continuous casting field test for 35 h, the damage of the ceramic type nozzle is mainly caused by the fracture in the service process for the poor thermal shock stability, cracks generating in the fracture process cause a certain degree of flaking and hole enlargement. Due to low strength and high apparent porosity, flaking and hole enlargement of the unmodified type particle metering nozzle is more serious. The thermal shock, scouring and erosion resistance of the particle type nozzle after being modified by Al2O3-ZrO2 composite powder improve remarkably because of the formation of MgAl2O4 spinel enhanced phase, but little hole enlargement occurs after casting test.

     

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