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混合稀土對Mg-9Y-0.6Zr鎂合金組織和性能的影響

Effects of mish-metal on microstructures and properties of a Mg-9Y-0.6Zr alloy

  • 摘要: 通過光學顯微鏡、X射線衍射儀(XRD)、描掃電鏡(SEM)、微分掃描量熱儀(DSC)和力學性能測試等手段,研究了加入質量分數為0%、1%、3%和5%混合稀土對Mg-9Y-0.6Zr(WK90)鎂合金組織及性能的影響.結果表明:鑄態WK90合金組織由α-Mg基體及少量的共晶組織構成,添加混合稀土后,晶界處的共晶組織明顯增多,并由單一共晶形式轉變為層狀共晶和離異共晶并存;隨著混合稀土添加量的增大,共晶組織的種類及數量增多,合金DSC曲線的低熔點吸熱峰總面積增大并最終發生分離;混合稀土為3%鑄態合金及含混合稀土為1%的擠壓態合金分別具有最高的斷裂強度,影響合金強度的因素除了晶粒尺寸外,離異共晶組織的分布狀態和形貌也是重要的因素.

     

    Abstract: The effects of 0%, 1%, 3% and 5% mish-metal additions on the microstructure and properties of an as-cast Mg-9Y-0.6Zr (WK90) alloy were investigated by optical microscope, X-ray diffractometer (XRD), scanning electron microscope (SEM), differential scanning calorimeter (DSC) and mechanical tester. The results indicate that the microstructure of the as-cast alloy is composed of α-Mg and little eutectic structure. After adding mish-metal, the eutectic structure increases markedly. When the mish-metal contents are 0%, 1% and 3%, the eutectic structure is in a single form, and there are the layered eutectic structure and the divorced eutectic structure when the mish-metal content is 5%. The areas of low temperature endothermic peaks in the DSC curves of WK90 alloy with different mish-metal contents increase and at last are separated with adding mish-metal, which is decided by the quantity and type of eutectic structure. The as-cast alloy with a mish-metal addition of 3% and the extruded alloy with a mish-metal addition of 1% have the best ultimate tensile strength under their own states. The influence reasons are not only grain size but also the distribution and the morphology of the divorced eutectic structure.

     

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