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Cl-對鍍鋅鋼板泥漿附著電偶保護距離的影響

Influence of Cl- on the galvanic protection distance of galvanized auto steel sheets covered with mud

  • 摘要: 采用酸性鷹潭土壤泥漿對部分鍍鋅層去除而暴露出基體的汽車鍍鋅鋼板進行了泥漿附著腐蝕實驗和電化學測試.在鋼的寬度相同的試樣上測定了陰極保護距離,并研究了在泥漿中添加不同含量Cl-的影響.結果發現:在不含Cl-的泥漿中陰極保護距離隨泥漿層厚度的增加而基本呈線性增加,出現紅銹的程度也相應減小;隨著Cl-含量和附著泥漿厚度的增加,陰極保護距離增加,并存在極大值.Cl-含量不僅影響著泥漿附著中的鍍鋅層破損試樣表面平均腐蝕電流密度,而且對泥漿中的溶氧量、pH值和電導率等參數都有影響.泥漿層厚度和Cl-含量決定著試樣的陰極保護距離和表面腐蝕狀態.

     

    Abstract: Galvanic protection distance (PD) and the effect of the addition of various contents of Cl- on it were studied with galvanized auto steel sheet specimens whose zinc coating was partly removed and covered with Ying-tan soil mud. The results show that in the mud without Cl- the PD value increase linearly with the thickness of mud layer, and the red-rust emerging time increases correspondingly. With increasing Cl- content and thickness of covered mud, the PD value raises and reaches a maximum. Cl- content influences not only the average corrosion current density, but also the dissolved oxygen, pH value and electrical conductivity. The thickness of mud layer and Cl- content control the PD value and surface corrosion state.

     

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