高飽和磁化強度鐵基非晶納米晶軟磁合金發展概況

惠希東; 呂曠; 斯佳佳; 杜晨曦; 王榮山

doi:10.13374/j.issn2095-9389.2018.10.002

高飽和磁化強度鐵基非晶納米晶軟磁合金發展概況

doi: 10.13374/j.issn2095-9389.2018.10.002

1) 北京科技大學新金屬材料國家重點實驗室, 北京 100083;
2) 蘇州熱工研究院有限公司, 蘇州 215004

基金項目:

十三五國家重點專項資助項目(15230007)

基因性團簇變異增韌鐵基非晶納米晶合金的理論研究資助項目(11298013)

詳細信息

中圖分類號: TG139⁺.8
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- 被引次數: 0
出版歷程
- 收稿日期: 2017-06-07

Development of Fe-based amorphous and nanocrystalline alloys with high saturation flux density

1) State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China;
2) Suzhou Nuclear Power Research Institute Co. Ltd., Suzhou 215004, China

摘要

摘要: 概括了鐵基非晶軟磁合金和納米晶合金的發展歷史和現狀,分別詳述了高飽和磁化強度(B_s)鐵基塊體和薄帶非晶以及納米晶合金近年來的研究成果.主要內容包括:高飽和磁化強度塊體鐵基非晶軟磁合金成分和性能,高飽和磁化強度鐵基非晶薄帶軟磁合金的成分和性能,高飽和磁化強度鐵基納米晶合金的組織、結構和性能,各類元素對合金磁性能的影響.為進一步研究高飽和磁化強度的鐵基軟磁材料提供了有價值的參考.
- 鐵基非晶合金 /
- 納米晶合金 /
- 高飽和磁化強度 /
- 成分 /
- 組織
Abstract: Iron-based amorphous alloys exhibit many desirable features, such as low coercivity, high permeability, high electrical resistivity, low loss, and good frequency characteristics, which make them a kind of viable energy-saving and environmentally-friendly materials. Their attractive features are due to their isotropic property, small structural correlation dimension, and magnetic anisotropic constant. The interactive coupling between the α-iron (Fe) nanocrystalline phase and amorphous soft magnetic phase further reduces the magnetic anisotropy and magnetostrictive effect of the Fe-based amorphous and nanocrystalline composites. Therefore, Fe-based amorphous and nanocrystalline alloys have a high saturation flux density and high magnetic permeability, and have been widely applied for electric power, electronics, and information transmission and conversion industries. Now, Fe-based amorphous and nanocrystalline alloys have been produced and applied to various areas on a large scale. In this paper, the development histories, situation, and tendency of Fe-based amorphous and nanocrystalline alloyswere briefly summarized. The research results of Fe-based bulk and ribbon amorphous alloys, along with nanocrystalline alloys with high saturation flux density (B_s), were reviewed in detail. The main contents of this paper include the compositions and properties of high-B_s Fe-based bulk and ribbon amorphous alloys; the compositions, structure and properties of high-B_s Fe-based nanocrystalline alloys; and the effects of alloying elements on the magnetic properties. These results will provide valuable insights that can be used for the development of Fe-based soft magnetic materials with a high saturation flux density.
- Fe-based amorphous alloy /
- nanocrystalline alloy /
- high saturation flux density /
- composition /
- microstructure

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參考文獻(56)

[1]	Luborsky F E. Applications of amorphous alloys.IEEE Trans Magn, 1978, 14(5):1008
[2]	Ng H W, Hasegawa R, Lee A C, et al. Amorphous alloy core distribution transformers.Proc IEEE, 1991, 79(11):1608
[3]	Hasegawa R. Applications of amorphous magnetic alloys.Mater Sci Eng A, 2004, 375-377:90
[4]	Gubanov A I. Quasi-classical theory of amorphous ferromagnetics.Sov Phys-Solid State, 1960, 2(3):468
[5]	Duwez P, Lin S C H. Amorphous ferromagnetic phase in iron-carbon-phosphorus alloys.J Appl Phys, 1967, 38(10):4096
[6]	Pond R J R, Maddin R. Method of producing rapidly solidified filamentary castings.Trans AIME, 1969, 245(11):2475
[7]	Makino A, Hatanai T, Inoue A, et al.Nanocrystalline soft magnetic Fe-M-B (M=Zr, Hf, Nb) alloys and their applications. Mater Sci Eng A, 1997, 226-228:594
[8]	Hasegawa R, O'Handley R C, Tanner L E, et al. Magnetization, magnetic anisotropy, and domain patterns of Fe₈₀B₂₀ glass. Appl Phys Lett, 1976, 29(3):219
[9]	Kabacoff L T. Thermal, magnetic, and magnetomechanical properties of Metglas 2605 S2 and S3.J Appl Phys, 1982, 53(11):8098
[10]	Spano M L, Hathaway K B, Savage H T. Magnetostriction and magnetic anisotropy of field annealed Metglas^* 2605 alloys via dc M-H loop measurements under stress. J Appl Phys, 1982, 53(3):2667
[11]	Bertotti G. General properties of power losses in soft ferromagnetic materials.IEEE Trans Magn, 1988, 24(1):621
[12]	Yoshizawa Y, Oguma S, Yamauchi K. New Fe-based soft magnetic alloys composed of ultrafine grain structure. J Appl Phys, 1988, 64(10):6044
[13]	Suzuki K, Makino A, Inoue A, et al. Soft magnetic properties of nanocrystalline bcc Fe-Zr-B and Fe-M-B-Cu (M=transition metal) alloys with high saturation magnetization. J Appl Phys, 1991, 70(10):6232
[14]	Makino A, Men H, Kubota T, et al. New Fe-metalloids based nanocrystalline alloys with high Bs of 1.9 T and excellent magnetic softness.J Appl Phys, 2009, 105(7):07A308
[15]	Hagiwara M, Inoue A, Masumoto T. Mechanical properties of Fe-Si-B amorphous wires produced by in-rotating-water spinning method. Metall Trans A, 1982, 13(3):373
[16]	Inoue A, Gook J S. Fe-based ferromagnetic glassy alloys with wide supercooled liquid region.Mater Trans JIM, 1995, 36(9):1180
[17]	Inoue A, Zhang T, Takeuchi A. Bulk amorphous alloys with high mechanical strength and good soft magnetic properties in Fe-TM-B (TM=IV-VⅢ group transition metal) system. Appl Phys Lett, 1997, 71(4):464
[18]	Zhang W, Inoue A. Thermal and magnetic properties of Fe-Co-Ln-B (Ln=Nd, Sm, Tb or Dy) amorphous alloys with high magnetostriction. Mater Trans JIM, 1999, 40(1):78
[19]	Zhang T, Inoue A. Bulk glassy alloys in (Fe, Co, Ni)-Si-B system. Mater Trans, 2001, 42(6):1015
[20]	Lin C Y, Tien H Y, Chin T S. Soft magnetic ternary iron-boron-based bulk metallic glasses.Appl Phys Lett, 2005, 86(16):162501
[21]	Shen B L, Akiba M, Inoue A. Excellent soft-ferromagnetic bulk glassy alloys with high saturation magnetization.Appl Phys Lett, 2006, 88(13):131907
[22]	Gao J E, Li H X, Jiao Z B, et al.Effects of nanocrystal formation on the soft magnetic properties of Fe-based bulk metallic glasses. Appl Phys Lett, 2011, 99(5):052504
[23]	O'handley R C, Hasegawa R, Ray R, et al. Ferromagnetic properties of some new metallic glasses.Appl Phys Lett, 1976, 29(6):330
[24]	Inoue A, Shen B L, Chang C T. Fe-and Co-based bulk glassy alloys with ultrahigh strength of over 4000 MPa.Intermetallics, 2006, 14(8-9):936
[25]	Inoue A, Zhang T, Takeuchi A. Bulk amorphous alloys with high mechanical strength and good soft magnetic properties in Fe-TM-B (TM=IV-VⅢ group transition metal) system. Appl Phys Lett, 1997, 71(4):464
[26]	Inoue A, Shen B L, Chang C T. Super-high strength of over 4000 MPa for Fe-based bulk glassy alloys in[(Fe_1-xCo_x)_0.75B_0.2Si_0.05]₉₆Nb₄ system. Acta Mater, 2004, 52(14):4093
[27]	Chang C T, Shen B L, Inoue A. FeNi-based bulk glassy alloys with superhigh mechanical strength and excellent soft-magnetic properties.Appl Phys Lett, 2006, 89(5):051912
[28]	Li F S, Shen B L, Makino A, et al. Excellent soft-magnetic properties of (Fe, Co)-Mo-(P, C, B, Si) bulk glassy alloys with ductile deformation behavior. Appl Phys Lett, 2007, 91(23):234101
[29]	Wang J F, Li R, Hua N B, et al.Ternary Fe-P-C bulk metallic glass with good soft-magnetic and mechanical properties. Scripta Mater, 2011, 65(6):536
[31]	Makino A, Kubota T, Chang C T, et al.FeSiBP bulk metallic glasses with unusual combination of high magnetization and high glass-forming ability. Mater Trans, 2007, 48(11):3024
[32]	Zhang J H, Chang C T, Wang A D, et al. Development of quaternary Fe-based bulk metallic glasses with high saturation magnetization above 1.6 T.J Non-Cryst Solids, 2012, 358(12-13):1443
[33]	Si J J, Mei J N, Wang R S, et al.Fe-B-Si-Zr bulk metallic glasses with ultrahigh compressive strength and excellent soft magnetic properties. Mater Lett, 2016, 181:282
[34]	Liu F J, Yao K F, Ding H Y. Fe-based glassy alloys with high iron content and high saturation magnetization.Intermetallics, 2011, 19(11):1674
[35]	Meng S Y, Ling H B, Li Q, et al. Development of Fe-based bulk metallic glasses with high saturation magnetization.Scripta Mater, 2014, 81:24
[37]	Wang A D, Zhao C L, Men H, et al. Fe-based amorphous alloys for wide ribbon production with high B_s and outstanding amorphous forming ability. J Alloys Compd, 2015, 630:209
[38]	Suzuki K, Kataoka N, Inoue A, et al.High saturation magnetization and soft magnetic properties of bcc Fe-Zr-B alloys with ultrafine grain structure. Mater Trans JIM, 1990, 31(8):743
[39]	Willard M A, Laughlin D E, McHenry M E, et al.Structure and magnetic properties of (Fe_0.5Co_0.5)₈₈Zr₇B₄Cu₁ nanocrystalline alloys. J Appl Phys, 1998, 84(12):6773
[40]	Ohta M, Yoshizawa Y.Magnetic properties of nanocrystalline Fe_82.65Cu_1.35Si_xB_16-x alloys (x=0-7). Appl Phys Lett, 2007, 91(6):062517
[41]	Ohta M, Yoshizawa Y. High B_s nanocrystalline Fe_84-x-yCu_xNb_ySi₄B₁₂ alloys (x=0.0-1.4, y=0.0-2.5). J Magn Magn Mater, 2009, 321(14):2220
[42]	Makino A, Men H, Kubota T, et al.New Fe-metalloids based nanocrystalline alloys with high B_s of 1.9 T and excellent magnetic softness. J Appl Phys, 2009, 105(7):07A308
[43]	Kong F L, Wang A D, Fan X D, et al.High Bs Fe_84-xSi₄B₈P₄Cu_x(x=0-1.5) nanocrystalline alloys with excellent magnetic softness. J Appl Phys, 2011, 109(7):07A303
[44]	Wang A D, Men H, Shen B L, et al.Effect of P on crystallization behavior and soft-magnetic properties of Fe_83.3Si₄Cu_0.7B_12-xP_x nanocrystalline soft-magnetic alloys. Thin Solid Films, 2011, 519(23):8283
[45]	Kong F L, Chang C T, Inoue A, et al.Fe-based amorphous soft magnetic alloys with high saturation magnetization and good bending ductility. J Alloys Compd, 2014, 615:163
[46]	Sharma P, Zhang X, Zhang Y, et al.Influence of microstructure on soft magnetic properties of low core loss and high B_sFe₈₅Si₂B₈P₄Cu₁ nanocrystalline alloy. J Appl Phys, 2014, 115(17):17A340
[47]	Liu W L, Wang Y G, Chen F G.Investigation of microstructure and magnetic properties of Fe₈₁Si₄B_12-xP₂Cu₁M_x(M=Cr, Mn and V; x=0,1,2,3) melt spun ribbons. J Alloys Compd, 2015, 622:751
[48]	Takenaka K, Setyawan A D, Sharma P, et al. Industrialization of nanocrystalline Fe-Si-B-P-Cu alloys for high magnetic flux density cores.J Magn Magn Mater, 2016, 401:479
[49]	Suzuki A, Makino A, Inoue A, et al. Soft magnetic properties of nanocrystalline bcc Fe-Zr-B and Fe-M-B-Cu (M=transition metal) alloys with high saturation magnetization. J Appl Phys, 1991, 70(10):6232
[50]	Ohta M, Yoshizawa Y. Magnetic properties of high-B_s Fe-Cu-Si-B nanocrystalline soft magnetic alloys. J Magn Magn Mater, 2008, 320(20):e750
[51]	Urata A, Yamaki M, Takahashi M, et al.Low core loss of non-Si quaternary Fe_83.3B₈P₈Cu_0.7 nanocrystalline alloy with high B_s of 1.7 T. J Appl Phys, 2012, 111(7):07A335
[52]	Li Z Z, Wang A D, Chang C T, et al.FeSiBPNbCu alloys with high glass-forming ability and good soft magnetic properties. Intermetallics, 2014, 54:225
[53]	Lopatina E, Soldatov I, Budinsky V, et al. Surface crystallization and magnetic properties of Fe_84.3Cu_0.7Si₄B₈P₃ soft magnetic ribbons. Acta Mater, 2015, 96:10
[54]	Xiang Z, Wang A D, Zhao C L, et al.Optimization of thermal stability and soft-magnetic properties of FeSiBPCuNb alloys by Nb content tuning. J Alloys Compd, 2015, 622:1000
[55]	Jafari S, Beitollahi A, Yekta B E, et al.Three-dimensional atom probe analysis and magnetic properties of Fe₈₅Cu₁Si₂B₈P₄ melt spun ribbons. J Magn Magn Mater, 2016, 401:1123
[56]	Han Y, Inoue A, Kong F L, et al.Softening and good ductility for nanocrystal-dispersed amorphous Fe-Co-B alloys with high saturation magnetization above 1.7 T. J Alloys Compd, 2016, 657:237
[57]	Li X L, Liu J B, Qu C R, et al.Effects of Nb on the precipitation of α-Fe, glass forming ability and magnetic properties of Fe₈₅B₁₀P₅ alloys. J Alloys Compd, 2017, 694:643
[58]	Xia G T, Wang Y G, Dai J, et al.Effects of Cu cluster evolution on soft magnetic properties of Fe₈₃B₁₀C₆Cu₁ metallic glass in two-step annealing. J Alloys Compd, 2017, 690:281