Preparation and properties of a binary composite water-soluble salt core for zinc alloy by die casting
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摘要: 針對復雜內腔鋅合金壓鑄件難清理及型芯強度要求高的問題,以高熔點鹽氯化鉀和低熔點鹽硝酸鉀組成混合鹽為制芯材料,采用熔融重力澆注工藝制備了高強度二元復合水溶性鹽芯.對比分析了氯化鉀鹽芯、硝酸鉀鹽芯和20% KCl-80% KNO3二元復合水溶性鹽芯的性能特征.采用掃描電鏡和X射線衍射等測試方法分析了水溶性鹽芯的微觀形貌與物相組成.研究結果表明:與單質鹽芯相比,二元復合鹽芯綜合性能更佳,其表面基本無裂紋與褶皺,抗彎強度可達21.2 MPa,24 h吸濕率為0.568%,80℃的水溶速率可達208.63 kg·min-1·m-3.復合鹽芯在裂紋擴展時走向發生了偏轉,這是復合鹽芯抗彎強度提高的主要原因.Abstract: For realizing complicated shapes of the inner cavity of zinc alloy castings by pressure die casting, the problem of poor leachability has to be solved and the high-strength requirement of the water-soluble salt core should be met. High-melting potassium chloride salt and low-melting potassium nitrate salt were used as the core materials. High-strength binary composite water-soluble salt core (WSSC) was formed by the process of melting and gravity pouring. The performance characteristics of the potassium chloride core, potassium nitrate core, and binary composite WSSC (20% KCl-80% KNO3) were investigated. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) studies were performed to examine the micro-morphology and phase composition of WSSC. The results indicate the following:the binary composite WSSC has excellent comprehensive performance, its bending strength can exceed 21.2 MPa, the 24 h hydroscopicity rate is 0.568%, the water-soluble rate can exceed 208.63 kg·min-1·m-3 in water at 80℃ and its surface has no cracks and folds unlike the pure salt core. Crack growth in the binary composite salt core occurs by deflection, which is the main reason for the improvement in bending strength.
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參考文獻
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