Preparation and microstructure analysis of CaO-MgO-SiO2 steel-slag ceramics
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摘要: 將鋼渣作為陶瓷的燒制原料之一,設計了CaO-MgO-SiO2體系陶瓷燒制配方,并成功地制備出性能穩定良好的陶瓷材料樣品.樣品的抗彎強度最大可達99.84 MPa.利用掃描電鏡、電子探針微區分析儀和X射線衍射儀等對鋼渣陶瓷制品進行了分析.結果發現:對于CaO-MgO-SiO2體系,當鋼渣加入量(質量分數)為40%時,主晶相為透輝石-鐵透輝石固溶體;當鋼渣加入量大于65%時,主晶相為鎂黃長石和透輝石.研究表明,采用鋼渣制備陶瓷材料是一種很有潛力的鋼渣高附加值利用技術.Abstract: A ceramic with stable and good performances was synthesized by designing the composition of the CaO-MgO-SiO2 system with steel slag as one of ceramic raw materials.Its bending strength can reach up to 99.84MPa.The ceramic samples were tested and analyzed by scanning electron microscopy(SEM),electron probe microanalysis(EPMA) and X-ray diffraction analysis(XRD).The results show that when the content of steel slag is 40% the dominated crystal phase in the ceramic is a solid solution of diopside and ferric diopside,but when the content of steel slag is higher than 65% the dominated crystal phases are akermanite and diopside.It is indicated that synthesizing a ceramic with steel slag is a promising technology for the utilization of steel slag with high added values.
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Key words:
- steel slag /
- solid wastes /
- waste utilization /
- ceramic materials /
- microstructure /
- diopside
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